A femtosecond study of the infrared-driven cis-trans isomerization of nitrous acid (HONO)

We investigate the dynamics and mechanism of the IR-driven cis-trans isomerization of nitrous acid (HONO) in a low-temperature krypton matrix applying ultrafast time resolved IR spectroscopy. After excitation of the OH-stretching mode the trans HONO state decays biexponentially on a 8 and 260 ps tim...

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Veröffentlicht in:	The Journal of chemical physics 2005-01, Vol.122 (4), p.44509-44509
Hauptverfasser:	Schanz, Roland, Boţan, Virgiliu, Hamm, Peter
Format:	Artikel
Sprache:	eng
Schlagworte:	ATOMIC AND MOLECULAR PHYSICS DEGREES OF FREEDOM EXCITED STATES ISOMERIZATION KRYPTON MATRIX ISOLATION NITROUS ACID PHOTOCHEMISTRY PROTONS REACTION KINETICS TIME RESOLUTION
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