Kinetic Study of Hydrolysis of Methylene Chloride from 100 to 500 °C

Kinetic Study of Hydrolysis of Methylene Chloride from 100 to 500 °C

Methylene chloride (CH2Cl2) is a representative model compound commonly found in aqueous wastes, process effluents, and contaminated soils and sediments. Oxidation in supercritical water provides a viable treatment and remediation pathway to convert CH2Cl2 to CO2, H2O, and HCl. However, in earlier w...

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Veröffentlicht in:Industrial & engineering chemistry research 1999-11, Vol.38 (11), p.4169-4174
Hauptverfasser: Salvatierra, Dolors, Taylor, Joshua D, Marrone, Philip A, Tester, Jefferson W
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
Chemistry
ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
ENVIRONMENTAL SCIENCES
Exact sciences and technology
HYDROLYSIS
Industrial wastewaters
Kinetics and mechanisms
LIQUID WASTES
MATHEMATICAL MODELS
METHYLENE CHLORIDE
NICKEL
Organic chemistry
Pollution
Reactivity and mechanisms
REMEDIAL ACTION
SUPERCRITICAL STATE
WASTE PROCESSING
Wastewaters
Water treatment and pollution
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Zusammenfassung:Methylene chloride (CH2Cl2) is a representative model compound commonly found in aqueous wastes, process effluents, and contaminated soils and sediments. Oxidation in supercritical water provides a viable treatment and remediation pathway to convert CH2Cl2 to CO2, H2O, and HCl. However, in earlier work, partial hydrolysis was observed at subcritical temperatures (
ISSN:0888-5885
1520-5045
DOI:10.1021/ie9903700