Robust palladium hydride catalyst for electrocatalytic formate formation with high CO tolerance

Robust palladium hydride catalyst for electrocatalytic formate formation with high CO tolerance

Palladium is unique in the electrocatalytic reduction of CO2 to formate because of its low or even near-equilibrium onset potential. However, the inevitably produced CO molecules poison and deactivate the catalyst surface, resulting in an insufficient operating lifetime (

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Bibliographische Detailangaben
Veröffentlicht in:Applied catalysis. B, Environmental Environmental, 2022-11, Vol.316, p.121659, Article 121659
Hauptverfasser: Guo, Shengyuan, Liu, Yuanchao, Murphy, Eamonn, Ly, Alvin, Xu, Mingjie, Matanovic, Ivana, Pan, Xiaoqing, Atanassov, Plamen
Format: Artikel
Sprache:eng
Schlagworte:
CO tolerance
Electrochemical CO2 reduction
Formate
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Palladium hydride
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Zusammenfassung:Palladium is unique in the electrocatalytic reduction of CO2 to formate because of its low or even near-equilibrium onset potential. However, the inevitably produced CO molecules poison and deactivate the catalyst surface, resulting in an insufficient operating lifetime (
ISSN:0926-3373
1873-3883
DOI:10.1016/j.apcatb.2022.121659