Copper(I)–Pyrazolate Complexes as Solid-State Phosphors: Deep-Blue Emission through a Remote Steric Effect

Copper(I)–Pyrazolate Complexes as Solid-State Phosphors: Deep-Blue Emission through a Remote Steric Effect

We describe a novel manifestation of rigidochromic behavior in a series of tetranuclear Cu­(I)–pyrazolate (Cu4pz4) macrocycles, with implications for solid-state luminescence at deep-blue wavelengths (

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Veröffentlicht in:Journal of the American Chemical Society 2022-06, Vol.144 (23), p.10186-10192
Hauptverfasser: Watanabe, Yuichiro, Washer, Benjamin M., Zeller, Matthias, Savikhin, Sergei, Slipchenko, Lyudmila V., Wei, Alexander
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
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Zusammenfassung:We describe a novel manifestation of rigidochromic behavior in a series of tetranuclear Cu­(I)–pyrazolate (Cu4pz4) macrocycles, with implications for solid-state luminescence at deep-blue wavelengths (
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.1c13462