High- χ diblock copolymers containing poly(vinylpyridine- N -oxide) segments

High- χ diblock copolymers containing poly(vinylpyridine- N -oxide) segments

Block copolymers exhibiting an enhanced segregation strength due to an underlying high Flory–Huggins interaction parameter (high χ ) have attracted considerable attention because of their potential of forming microphase-separated domains with very small feature sizes (

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2023-05, Vol.11 (18), p.9846-9858
Hauptverfasser: Angelopoulou, Polyxeni P., Kearney, Logan T., Keum, Jong K., Collins, Liam, Kumar, Rajeev, Sakellariou, Georgios, Advincula, Rigoberto C., Mays, Jimmy W., Hong, Kunlun
Format: Artikel
Sprache:eng
Schlagworte:
Block copolymers
Copolymers
Dipole moments
Domains
Interaction parameters
Lamellar structure
Low molecular weights
Molecular weight
Morphology
Oxidation
Polystyrene resins
Polyvinyl pyridine
Precursors
Segments
Self-assembly
Styrene
Styrenes
Thin films
Transition temperature
Transition temperatures
X-ray scattering
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Beschreibung
Zusammenfassung:Block copolymers exhibiting an enhanced segregation strength due to an underlying high Flory–Huggins interaction parameter (high χ ) have attracted considerable attention because of their potential of forming microphase-separated domains with very small feature sizes (
ISSN:2050-7488
2050-7496
DOI:10.1039/D3TA01386C