Unimolecular Kinetics of Stabilized CH 3 CHOO Criegee Intermediates: syn -CH 3 CHOO Decomposition and anti -CH 3 CHOO Isomerization

The kinetics of the unimolecular decomposition of the stabilized Criegee intermediate syn-CH3CHOO has been investigated at temperatures between 297 and 331 K and pressures between 12 and 300 Torr using laser flash photolysis of CH3CHI2/O2/N2 gas mixtures coupled with time-resolved broadband UV absor...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2022-10, Vol.126 (39), p.6984-6994
Hauptverfasser:	Robinson, Callum, Onel, Lavinia, Newman, James, Lade, Rachel, Au, Kendrew, Sheps, Leonid, Heard, Dwayne E., Seakins, Paul W., Blitz, Mark A., Stone, Daniel
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Kinetics Organic reactions Photodissociation Tunneling
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