KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency

KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency

A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF·B(OH) 3 , has been discovered. The well-aligned [F·B(OH) 3 ] − layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer bonding of ca. 2.16...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (63), p.8770-8773
Hauptverfasser: Li, Yang, Chen, Xinglong, Ok, Kang Min
Format: Artikel
Sprache:eng
Schlagworte:
Birefringence
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Interlayers
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Zusammenfassung:A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF·B(OH) 3 , has been discovered. The well-aligned [F·B(OH) 3 ] − layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer bonding of ca. 2.16 × KBe 2 BO 3 F 2 .
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc03495f