Dimethylcarbene versus Direct Propene Formation in Dimethylketene Photodissociation

Highly reactive carbenes are usually produced by photolysis of ketenes, diazoalkanes, or diazirines. Sequential kinetic pathways for deactivation of nascent carbenes usually involve bimolecular reactions in competition with isomerization producing stable products such as alkenes. However, the direct...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2021-08, Vol.125 (32), p.6940-6948
Hauptverfasser:	Datta, Sagnik, Davis, H. Floyd
Format:	Artikel
Sprache:	eng
Schlagworte:	A: Structure, Spectroscopy, and Reactivity of Molecules and Clusters Chemistry Physics
Online-Zugang:	Volltext
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