Etching and polymerization reactions of alkoxythiophenes in HKUST-1: choosing between filled and core–shell MOF/polymer composite structures

Neat alkoxythiophenes react with MOF HKUST-1 to form a core–shell composite where the HKUST-1 surface is coated with conjugated polymer, while hexane solutions of thiophenes form a filled composite with polythiophene inside MOF pores.

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Veröffentlicht in:CrystEngComm 2021-01, Vol.23 (28)
Hauptverfasser: James, William, Sullivan, Colette M., Marshall, Nicholas
Format: Artikel
Sprache:eng
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Zusammenfassung:Neat alkoxythiophenes react with MOF HKUST-1 to form a core–shell composite where the HKUST-1 surface is coated with conjugated polymer, while hexane solutions of thiophenes form a filled composite with polythiophene inside MOF pores.
ISSN:1466-8033
1466-8033