Thermodynamically consistent algorithms for models of incompressible multiphase polymer solutions with a variable mobility

We present a general strategy for developing structure and property preserving numerical algorithms for thermodynamically consistent models of incompressible multiphase polymer solutions with a variable mobility. We first present a formalism to derive thermodynamically consistent, incompressible, mu...

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Veröffentlicht in:Journal of computational and applied mathematics 2021-10, Vol.395 (C), p.113573, Article 113573
Hauptverfasser: Shen, Xiaowen, Wang, Qi
Format: Artikel
Sprache:eng
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Zusammenfassung:We present a general strategy for developing structure and property preserving numerical algorithms for thermodynamically consistent models of incompressible multiphase polymer solutions with a variable mobility. We first present a formalism to derive thermodynamically consistent, incompressible, multiphase polymer models. Then, we develop the general strategy, known as the supplementary variable method, to devise thermodynamically consistent numerical approximations to the models. We illustrate the numerical strategy using newly developed models of incompressible diblock copolymer solutions coupled with an electric and a magnetic field, respectively. Mesh refinement is conducted to verify convergence rates of the developed schemes. Some numerical examples are given to exhibit underlying dynamics absent from and driven by the external fields, respectively, highlighting differences between models with the variable and constant mobilities.
ISSN:0377-0427
1879-1778
DOI:10.1016/j.cam.2021.113573