Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand

Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand

Uranyl–carbon bonds are rare due to the limited numbers of synthetic routes. The synthesis of carbodicarbene uranyl complexes is reported, along with complete spectroscopic and structural characterization. These data along with a computational analysis confirm strong electron donation by the carbodi...

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Veröffentlicht in:Organometallics 2020-03, Vol.39 (6), p.783-787
Hauptverfasser: Maity, Arnab K, Ward, Robert J, Rupasinghe, D. M. Ramitha Y. P, Zeller, Matthias, Walensky, Justin R, Bart, Suzanne C
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container_end_page 787
container_issue 6
container_start_page 783
container_title Organometallics
container_volume 39
creator Maity, Arnab K
Ward, Robert J
Rupasinghe, D. M. Ramitha Y. P
Zeller, Matthias
Walensky, Justin R
Bart, Suzanne C
description Uranyl–carbon bonds are rare due to the limited numbers of synthetic routes. The synthesis of carbodicarbene uranyl complexes is reported, along with complete spectroscopic and structural characterization. These data along with a computational analysis confirm strong electron donation by the carbodicarbene ligand, as well as a single-bond order between the uranium­(VI) ion and the carbon.
doi_str_mv 10.1021/acs.organomet.9b00860
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title Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand
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