Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand

Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand

Uranyl–carbon bonds are rare due to the limited numbers of synthetic routes. The synthesis of carbodicarbene uranyl complexes is reported, along with complete spectroscopic and structural characterization. These data along with a computational analysis confirm strong electron donation by the carbodi...

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Veröffentlicht in:Organometallics 2020-03, Vol.39 (6), p.783-787
Hauptverfasser: Maity, Arnab K, Ward, Robert J, Rupasinghe, D. M. Ramitha Y. P, Zeller, Matthias, Walensky, Justin R, Bart, Suzanne C
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
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Zusammenfassung:Uranyl–carbon bonds are rare due to the limited numbers of synthetic routes. The synthesis of carbodicarbene uranyl complexes is reported, along with complete spectroscopic and structural characterization. These data along with a computational analysis confirm strong electron donation by the carbodicarbene ligand, as well as a single-bond order between the uranium­(VI) ion and the carbon.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.9b00860