The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework

The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework

1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (43), p.5737-5740
Hauptverfasser: Taddei, Marco, Costantino, Ferdinando, Vivani, Riccardo, Sabatini, Stefano, Lim, Sang-Ho, Cohen, Seth M
Format: Artikel
Sprache:eng
Schlagworte:
Heating
Hydrolysis
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ligands
Microwaves
Phosphonates
Robustness
Synthesis
Zirconium
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Beschreibung
Zusammenfassung:1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01253d