Bis(1,2,4‐oxadiazolyl) Furoxan: A Promising Melt‐Castable Eutectic Material of Low Sensitivity
A scalable synthesis of bis(1,2,4‐oxadiazoyl) furoxan, C6H2N6O4, its physical properties, and its theoretical performance values are described. Previous attempts to synthesize this compound required expensive reagents, and/or time‐consuming synthesis processes and low overall yields. In addition to...
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Veröffentlicht in: | ChemPlusChem (Weinheim, Germany) Germany), 2019-04, Vol.84 (4), p.319-322 |
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Sprache: | eng |
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Zusammenfassung: | A scalable synthesis of bis(1,2,4‐oxadiazoyl) furoxan, C6H2N6O4, its physical properties, and its theoretical performance values are described. Previous attempts to synthesize this compound required expensive reagents, and/or time‐consuming synthesis processes and low overall yields. In addition to disclosing a streamlined synthesis of bis(1,2,4‐oxadiazolyl) furoxan, we report its molecular configuration and crystal structure, as well as its correct melting point. Bis(1,2,4‐oxadiazolyl) furoxan exhibits a very insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure 20 % higher than that of TNT. Given its physical properties and theoretical performance values, this material can be classified as a promising ingredient in the development of melt‐castable eutectic technology.
A melt‐castable eutectic: A scalable synthesis of bis(1,2,4‐oxadiazolyl) furoxan, C6H2N6O4, its physical properties, and its theoretical performance values are described. This material displays a calculated detonation pressure 20 % higher than TNT, and is very insensitive to impact, friction, and electrostatic discharge. The material is classified as an insensitive explosive ingredient that could find application in melt‐castable eutectic formulations. |
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ISSN: | 2192-6506 2192-6506 |
DOI: | 10.1002/cplu.201800563 |