Bipropellant high energy stimulation for oil and gas applications

Large-scale extraction of oil and natural gas requires an effective method of generating a high surface area network of fractures, or the stimulation of existing fractures, in a formation in order to increase permeability. Conventional hydraulic fracturing has limited utility in this application. In this work, Sandia National Laboratories is exploring high rate pressurization techniques employing tailored energetic materials systems to control both pressure rise rate and peak pressure in order to optimally stimulate potential rock formations. Rapid pressurization, at rates far exceeding quasi-static conventional hydraulic rates, can generate multiple radial well bore fractures and potentially provide a mechanism to induce shear destabilization within the formation that enables the fractures to be self-propping. Multiple fractures from the well bore allow efficient coupling to the existing formation fracture network and increase near field well bore permeability. Furthermore, these techniques can allow for repeated stimulations and produce energetic events within the fractures thereby allowing fractures to be extended further. Controlled rate pressurization is a useful tool for the efficient generation of fracture networks and has potential application to increase oil and gas production. This paper provides an overview of the concept of controlled rate pressurization, laboratory experiments and field trials that are being conducted. The present work investigates detonations of a stoichiometric mixture of ethylene and nitrous oxide (C2H4 + 6N2O) at high initial pressures ranging from 0.862 to 2.068 MPa as a method of fracturing rock below the ground surface. The experiments investigate the fracture generation as a function of the initial pressure of the mixture. In the current configuration, the combustion reaction is initiated by an electrically fired igniter at the ground surface and quickly transitions to a detonation. The experimental setup accommodates one high pressure (690 MPa) transducer, placed downstream of the igniter, to measure peak pressure. The pressure transducer recorded peak pressures, which are 2.3–2.6 times in excess of the Chapman-Jouguet (CJ) values as a result of pre-compression of the unburned gas mixture during the flame acceleration prior to deflagration-to-detonation transition (DDT). Analysis of the data indicated an increase in rock permeability due to detonations and this was confirmed by the core drilled sections at the test si