Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage
A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO22+) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediat...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-07, Vol.54 (68) |
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| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO22+) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediates the transformation of cage-1 to cage-2 via the activation of molecular oxygen here. |
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| ISSN: | 1359-7345 1364-548X |