The effect of cooling rate on magnetothermal properties of Fe49Rh51
•Two bulk Fe49Rh51 samples produced by two different temperature regimes.•Rapidly quenched (FQ) in iced-water and slow cooled (SC) with rate of 2 K/min.•The effects of cooling rate on the phase transition in Fe49Rh51 were studied.•The temperature of the AFM-FM transition was similar for FQ and SC sa...
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Veröffentlicht in: | Journal of magnetism and magnetic materials 2020-03, Vol.498, p.166130, Article 166130 |
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Sprache: | eng |
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Zusammenfassung: | •Two bulk Fe49Rh51 samples produced by two different temperature regimes.•Rapidly quenched (FQ) in iced-water and slow cooled (SC) with rate of 2 K/min.•The effects of cooling rate on the phase transition in Fe49Rh51 were studied.•The temperature of the AFM-FM transition was similar for FQ and SC samples.•Difference in ΔSM(T) curves and magnetization change: sharper changes for FQ sample.•Difference on hysteresis losses values is shown.
We have investigated the effects of quenching rate on the thermal dependence of the magnetic entropy change ΔSM(T) and the magnetic field induced hysteresis loss through the antiferromagnetic (AFM) ↔ ferromagnetic (FM) transformation in bulk Fe49Rh51. Two nearly identical square-prism-shaped samples were subjected to two different temperature cooling regimes; one was rapidly quenched (FQ) in iced-water and another slow cooled (SC) to room temperature at a cooling rate of 2 K/min. The temperature of the AFM ↔ FM transition is similar for both samples, but the FQ sample shows much sharper temperature- and magnetic field-induced magnetization change; in addition, the total magnetization change is 14% larger. In FQ material, the magnetocaloric effect, i.e., ΔSM(T) quickly approaches saturation above 1 T and shows a large peak value at 2 T (13.9 versus 8.9 Jkg−1 K−1 in SC material), but a larger average hysteresis loss FWHM in the temperature range coinciding with of the full-width at half-maximum of the ΔSM(T) curve. |
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ISSN: | 0304-8853 1873-4766 |
DOI: | 10.1016/j.jmmm.2019.166130 |