A reduction series of neodymium supported by pyridine(diimine) ligands
The synthesis of a redox series of neodymium species bearing the redox active pyridine(diimine) ligand, Mes PDI Me , is reported. Spectroscopic and structural characterization supports each compound has a Nd( iii ) centre, with the Mes PDI Me ligand existing in four oxidation states. A series of red...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-06, Vol.48 (23), p.821-825 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Galley, Shane S Pattenaude, Scott A Higgins, Robert F Tatebe, Caleb J Stanley, Dalton A Fanwick, Phillip E Zeller, Matthias Schelter, Eric J Bart, Suzanne C |
| description | The synthesis of a redox series of neodymium species bearing the redox active pyridine(diimine) ligand,
Mes
PDI
Me
, is reported. Spectroscopic and structural characterization supports each compound has a Nd(
iii
) centre, with the
Mes
PDI
Me
ligand existing in four oxidation states.
A series of reduced PDI neodymium complexes by the PDI ligand acting as an electron sink. |
| doi_str_mv | 10.1039/c9dt00679f |
| format | Article |
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Mes
PDI
Me
, is reported. Spectroscopic and structural characterization supports each compound has a Nd(
iii
) centre, with the
Mes
PDI
Me
ligand existing in four oxidation states.
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Mes
PDI
Me
, is reported. Spectroscopic and structural characterization supports each compound has a Nd(
iii
) centre, with the
Mes
PDI
Me
ligand existing in four oxidation states.
A series of reduced PDI neodymium complexes by the PDI ligand acting as an electron sink.</description><subject>Absorption spectra</subject><subject>Crystallography</subject><subject>Ligands</subject><subject>Neodymium</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Oxidation</subject><subject>Spectroscopy</subject><subject>Structural analysis</subject><subject>Supports</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp90c1LwzAYBvAgit8X70rVyxSmb5I2bY5jOhUGXuY5tPnQjLWpSXvof290OsGDpzeQHw-874PQCYYbDJTfSq46AJZzs4X2cZrnY05our15E7aHDkJYAhACGdlFexQDAV7APppNEq9VLzvrmiRob3VInEka7dRQ275OQt-2zndaJdWQtIO3yjZ6pKyt47xKVva1bFQ4QjumXAV9_D0P0cvsfjF9HM-fH56mk_lY0hSbcVUVZVpQjHVhUgUZlJQAoxqkkqRMcwYkA1VhamiGMac548pwprDKcMlyQg_RxTrXhc6KIG2n5Zt0TaNlJ3AGRcFYRKM1ar1773XoRG2D1KtVGdfqgyAkSlKk_DPv8g9dut43cYWoaF7geDwa1fVaSe9C8NqI1tu69IPAID4rEFN-t_iqYBbx2XdkX9VabejPzSM4XwMf5Ob3t0PRKhPN6X-GfgBGU5PS</recordid><startdate>20190611</startdate><enddate>20190611</enddate><creator>Galley, Shane S</creator><creator>Pattenaude, Scott A</creator><creator>Higgins, Robert F</creator><creator>Tatebe, Caleb J</creator><creator>Stanley, Dalton A</creator><creator>Fanwick, Phillip E</creator><creator>Zeller, Matthias</creator><creator>Schelter, Eric J</creator><creator>Bart, Suzanne C</creator><general>Royal Society of Chemistry</general><general>Royal Society of Chemistry (RSC)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-7817-388X</orcidid><orcidid>https://orcid.org/0000-0001-6776-3537</orcidid><orcidid>https://orcid.org/0000-0003-0679-6567</orcidid><orcidid>https://orcid.org/0000-0002-3305-852X</orcidid><orcidid>https://orcid.org/0000-0002-8918-9051</orcidid><orcidid>https://orcid.org/0000-0002-0564-2796</orcidid><orcidid>https://orcid.org/0000-0002-8143-6206</orcidid><orcidid>https://orcid.org/0000000289189051</orcidid><orcidid>https://orcid.org/0000000205642796</orcidid><orcidid>https://orcid.org/000000023305852X</orcidid><orcidid>https://orcid.org/0000000306796567</orcidid><orcidid>https://orcid.org/0000000281436206</orcidid><orcidid>https://orcid.org/000000027817388X</orcidid><orcidid>https://orcid.org/0000000167763537</orcidid></search><sort><creationdate>20190611</creationdate><title>A reduction series of neodymium supported by pyridine(diimine) ligands</title><author>Galley, Shane S ; 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Mes
PDI
Me
, is reported. Spectroscopic and structural characterization supports each compound has a Nd(
iii
) centre, with the
Mes
PDI
Me
ligand existing in four oxidation states.
A series of reduced PDI neodymium complexes by the PDI ligand acting as an electron sink.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31020980</pmid><doi>10.1039/c9dt00679f</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7817-388X</orcidid><orcidid>https://orcid.org/0000-0001-6776-3537</orcidid><orcidid>https://orcid.org/0000-0003-0679-6567</orcidid><orcidid>https://orcid.org/0000-0002-3305-852X</orcidid><orcidid>https://orcid.org/0000-0002-8918-9051</orcidid><orcidid>https://orcid.org/0000-0002-0564-2796</orcidid><orcidid>https://orcid.org/0000-0002-8143-6206</orcidid><orcidid>https://orcid.org/0000000289189051</orcidid><orcidid>https://orcid.org/0000000205642796</orcidid><orcidid>https://orcid.org/000000023305852X</orcidid><orcidid>https://orcid.org/0000000306796567</orcidid><orcidid>https://orcid.org/0000000281436206</orcidid><orcidid>https://orcid.org/000000027817388X</orcidid><orcidid>https://orcid.org/0000000167763537</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-06, Vol.48 (23), p.821-825 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1508866 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Absorption spectra Crystallography Ligands Neodymium NMR Nuclear magnetic resonance Oxidation Spectroscopy Structural analysis Supports |
| title | A reduction series of neodymium supported by pyridine(diimine) ligands |
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