A reduction series of neodymium supported by pyridine(diimine) ligands

A reduction series of neodymium supported by pyridine(diimine) ligands

The synthesis of a redox series of neodymium species bearing the redox active pyridine(diimine) ligand, Mes PDI Me , is reported. Spectroscopic and structural characterization supports each compound has a Nd( iii ) centre, with the Mes PDI Me ligand existing in four oxidation states. A series of red...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2019-06, Vol.48 (23), p.821-825
Hauptverfasser: Galley, Shane S, Pattenaude, Scott A, Higgins, Robert F, Tatebe, Caleb J, Stanley, Dalton A, Fanwick, Phillip E, Zeller, Matthias, Schelter, Eric J, Bart, Suzanne C
Format: Artikel
Sprache:eng
Schlagworte:
Absorption spectra
Crystallography
Ligands
Neodymium
NMR
Nuclear magnetic resonance
Oxidation
Spectroscopy
Structural analysis
Supports
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Zusammenfassung:The synthesis of a redox series of neodymium species bearing the redox active pyridine(diimine) ligand, Mes PDI Me , is reported. Spectroscopic and structural characterization supports each compound has a Nd( iii ) centre, with the Mes PDI Me ligand existing in four oxidation states. A series of reduced PDI neodymium complexes by the PDI ligand acting as an electron sink.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt00679f