Effect of flow field geometry on operating current density, capacity and performance of vanadium redox flow battery

Addition of flow fields to carbon paper electrodes in a vanadium redox flow battery (VRFB) can improve the peak power density through uniform distribution of electrolyte in the electrodes. However, it is unclear whether flow fields have a similar effect with graphite felt electrodes, as VRFBs with f...

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Veröffentlicht in:Journal of power sources 2018-11, Vol.404 (C), p.20-27
Hauptverfasser: Maurya, Sandip, Nguyen, Phong Thanh, Kim, Yu Seung, Kang, Qinjun, Mukundan, Rangachary
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Sprache:eng
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Zusammenfassung:Addition of flow fields to carbon paper electrodes in a vanadium redox flow battery (VRFB) can improve the peak power density through uniform distribution of electrolyte in the electrodes. However, it is unclear whether flow fields have a similar effect with graphite felt electrodes, as VRFBs with felt electrodes reported in literature show a large anomaly in obtained power density. In this work, we evaluate three flow fields; viz. serpentine, interdigitated and conventional (without flow pattern) type with felt electrodes and compare their performance with a serpentine flow field using carbon paper electrodes under identical experimental conditions. The conventional flow field provides highest energy efficiency (75%) followed by serpentine (64%) and interdigitated (55%) at 0.2 A cm−2 attributable to the deteriorating electrolyte distribution in the electrodes. Computation fluid dynamic simulations confirm the experimental finding of worsening electrolyte distribution (conventional 
ISSN:0378-7753
1873-2755
DOI:10.1016/j.jpowsour.2018.09.093