Four-Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production

The reaction of ozone with isoprene, one of the most abundant volatile organic compounds in the atmosphere, produces three distinct carbonyl oxide species (RR′COO) known as Criegee intermediates: formaldehyde oxide (CH2OO), methyl vinyl ketone oxide (MVK-OO), and methacrolein oxide (MACR-OO). The na...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-08, Vol.140 (34), p.10866-10880
Hauptverfasser:	Barber, Victoria P, Pandit, Shubhrangshu, Green, Amy M, Trongsiriwat, Nisalak, Walsh, Patrick J, Klippenstein, Stephen J, Lester, Marsha I
Format:	Artikel
Sprache:	eng
Schlagworte:	Creigee Intermediate Isoprene ozonolysis Unimolecular reactions
Online-Zugang:	Volltext
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