A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.

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Veröffentlicht in:Magnetochemistry 2016-02, Vol.2 (1), p.9
Hauptverfasser: Shepherd, Helena, Tonge, George, Hatcher, Lauren, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin, Teat, Simon
Format: Artikel
Sprache:eng
Schlagworte:
Behavior
Chemistry
Crossovers
Ligands
Order disorder
Phase transitions
Temperature
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Zusammenfassung:A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.
ISSN:2312-7481
2312-7481
DOI:10.3390/magnetochemistry2010009