Substituent Effects in the Pyridinium Catalyzed Reduction of CO2 to Methanol: Further Mechanistic Insights

A series of substituted pyridiniums were examined for their catalytic ability to electrochemically reduce carbon dioxide to methanol. It is found that in general increased basicity of the nitrogen of the amine and higher LUMO energy of the pyridinium correlate with enhanced carbon dioxide reduction....

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Veröffentlicht in:Topics in catalysis 2014-11, Vol.58 (1)
Hauptverfasser: Barton Cole, Emily E., Baruch, Maor F., L’Esperance, Robert P., Kelly, Michael T., Lakkaraju, Prasad S., Zeitler, Elizabeth L., Bocarsly, Andrew B.
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Sprache:eng
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