A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridiniu...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-09, Vol.53 (78), p.10816-10819
Hauptverfasser: Surbella, Robert G, Ducati, Lucas C, Pellegrini, Kristi L, McNamara, Bruce K, Autschbach, Jochen, Schwantes, Jon M, Cahill, Christopher L
Format: Artikel
Sprache:eng
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INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Zusammenfassung:Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc05988d