Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)
The reaction of (C Me ) AnCl (An = Th, U) with 2.8 or 4 equivalents of LiNMe , respectively, affords (C Me ) An(NMe ) in high yields. In addition to improved syntheses, the solid-state structures, voltammetric data, and UV-visible-NIR spectra for these classic actinide bis(dimethylamido) complexes a...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2017-08, Vol.46 (34), p.11208-11213 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The reaction of (C
Me
)
AnCl
(An = Th, U) with 2.8 or 4 equivalents of LiNMe
, respectively, affords (C
Me
)
An(NMe
)
in high yields. In addition to improved syntheses, the solid-state structures, voltammetric data, and UV-visible-NIR spectra for these classic actinide bis(dimethylamido) complexes are presented for the first time. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c7dt02373a |