Uniform second Li ion intercalation in solid state ϵ -LiVOPO 4

Full, reversible intercalation of two Li+ has not yet been achieved in promising VOPO4 electrodes. A pronounced Li+ gradient has been reported in the low voltage window (i.e. second lithium reaction) that is thought to originate from disrupted kinetics in the high voltage regime (i.e first lithium r...

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Veröffentlicht in:Applied physics letters 2016-08, Vol.109 (5)
Hauptverfasser: Wangoh, Linda W., Sallis, Shawn, Wiaderek, Kamila M., Lin, Yuh-Chieh, Wen, Bohua, Quackenbush, Nicholas F., Chernova, Natasha A., Guo, Jinghua, Ma, Lu, Wu, Tianpin, Lee, Tien-Lin, Schlueter, Christoph, Ong, Shyue Ping, Chapman, Karena W., Whittingham, M. Stanley, Piper, Louis F. J.
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Sprache:eng
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Zusammenfassung:Full, reversible intercalation of two Li+ has not yet been achieved in promising VOPO4 electrodes. A pronounced Li+ gradient has been reported in the low voltage window (i.e. second lithium reaction) that is thought to originate from disrupted kinetics in the high voltage regime (i.e first lithium reaction). Here we employ a combination of hard and soft x–ray photoelectron and absorption spectroscopy techniques to depth profile solid state synthesized LiVOPO4 cycled within the low voltage window only. Analysis of the vanadium environment revealed no evidence of a Li+ gradient, which combined with almost full theoretical capacity confirms that disrupted kinetics in the high voltage window are responsible for hindering full two lithium insertion. Furthermore, we argue that the uniform Li+ intercalation is a prerequisite for the formation of intermediate phases Li1:50VOPO4 and Li1:75VOPO4. The evolution from LiVOPO4 to Li2VOPO4 via the intermediate phases is confirmed by direct comparison between O K–edge absorption spectroscopy and density functional theory.
ISSN:0003-6951
1077-3118