Arranging pseudorotaxanes octahedrally around [60]fullerene

Arranging pseudorotaxanes octahedrally around [60]fullerene

The formation of both [2]- and [7]pseudorotaxanes, which are obtained by mixing of a dibenzylammonium derivative with mono- and hexakis-adducts of [60]fullerene bearing malonato-benzo[25]crown-8 rings, has been monitored in dichloromethane by both 1D and 2D (1)H NMR spectroscopies.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (5), p.1425-1427
Hauptverfasser: Dey, Sanjeev K, Beuerle, Florian, Olson, Mark A, Stoddart, J Fraser
Format: Artikel
Sprache:eng
Schlagworte:
Bearing
catalysis (homogeneous), solar (photovoltaic), bio-inspired, charge transport, mesostructured materials, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
Derivatives
Dichloromethane
NMR spectroscopy
Two dimensional
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Zusammenfassung:The formation of both [2]- and [7]pseudorotaxanes, which are obtained by mixing of a dibenzylammonium derivative with mono- and hexakis-adducts of [60]fullerene bearing malonato-benzo[25]crown-8 rings, has been monitored in dichloromethane by both 1D and 2D (1)H NMR spectroscopies.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc03963b