Iridium( iii ) catalyzed trifluoroacetoxylation of aromatic hydrocarbons

Iridium( iii ) catalyzed trifluoroacetoxylation of aromatic hydrocarbons

A tridentate, NNC-tb (where NNC-tb = 2-(pyridin-2-yl)benzo[h]quinoline) ligated IrIIIcomplex (NNC-tb)Ir(Ph)(4-MePy)(TFA),11along with analogues are very active for CH activation as evidenced by rapid catalytic H/D exchange between benzene and trifluoroacetic acid – d1(DTFA).

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Veröffentlicht in:RSC advances 2014-01, Vol.4 (67)
Hauptverfasser: Bischof, Steven M., Hashiguchi, Brian G., Lokare, Kapil S., Gunsalus, Niles, Yousufuddin, Mohammed, Periana, Roy A.
Format: Artikel
Sprache:eng
Schlagworte:
catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)
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Zusammenfassung:A tridentate, NNC-tb (where NNC-tb = 2-(pyridin-2-yl)benzo[h]quinoline) ligated IrIIIcomplex (NNC-tb)Ir(Ph)(4-MePy)(TFA),11along with analogues are very active for CH activation as evidenced by rapid catalytic H/D exchange between benzene and trifluoroacetic acid – d1(DTFA).
ISSN:2046-2069
2046-2069
DOI:10.1039/c4ra06251e