Vibrational dynamics (IR, Raman, NRVS) and DFT study of new antitumor tetranuclearstannoxanecluster, Sn(IV)$-$oxo$-${di$-$o$-$vanillin} dimethyl dichloride

The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2016-06, Vol.18 (27)
Hauptverfasser: Arjmand, F., Sharma, S., Usman, M., Leu, B. M., Hu, M. Y., Toupet, L., Gosztola, David J., Tabassum, S.
Format: Artikel
Sprache:eng
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Zusammenfassung:The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity revealed a significant regression selectively against the human pancreatic cell lines.
ISSN:1463-9076
1463-9084
DOI:10.1039/c6cp02914k