Electroluminescence and the measurement of temperature during Stage III of flash sintering experiments

The optical glow of ceramics that becomes established during the constant state of flash, known as Stage III in flash sintering experiments, is investigated. The specimen temperature in this state is obtained from in situ experiments at the Pohang Light Source II. The measurements of the specimen temperature agree very well with the predictions from the black body radiation model. The optical emission spectrum from the specimen is measured from the visible into the deep infrared, and compared with black body radiation that would have been expected from Joule heating. It is concluded that the specimens radiate by electroluminescence, which is ascribed to electron–hole recombination of excitons. The phenomenon is likely the same as discovered by Nernst at the turn of the twentieth century.