The crystalline sponge method: MOF terminal ligand effects

The crystalline sponge method: MOF terminal ligand effects

Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(-)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (56), p.11252-11255
Hauptverfasser: Ramadhar, Timothy R, Zheng, Shao-Liang, Chen, Yu-Sheng, Clardy, Jon
Format: Artikel
Sprache:eng
Schlagworte:
Analogs
Chemistry
Chlorides
Crystal structure
Crystallization
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Sponges
Synchrotron radiation
Terminals
Zinc
Zinc - chemistry
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Beschreibung
Zusammenfassung:Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(-)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc03840e