Measuring disorder in irreversible decay processes

Rate coefficients can fluctuate in statically and dynamically disordered kinetics. Here, we relate the rate coefficient for an irreversibly decaying population to the Fisher information. From this relationship we define kinetic versions of statistical-length squared and divergence that measure cumul...

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Veröffentlicht in:The Journal of chemical physics 2014-09, Vol.141 (10), p.104107-104107
Hauptverfasser: Flynn, Shane W, Zhao, Helen C, Green, Jason R
Format: Artikel
Sprache:eng
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Zusammenfassung:Rate coefficients can fluctuate in statically and dynamically disordered kinetics. Here, we relate the rate coefficient for an irreversibly decaying population to the Fisher information. From this relationship we define kinetic versions of statistical-length squared and divergence that measure cumulative fluctuations in the rate coefficient. We show the difference between these kinetic quantities measures the amount of disorder, and is zero when the rate coefficient is temporally and spatially unique.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.4895514