Glass-Like Thermal Conductivity of (010)-Textured Lanthanum-Doped Strontium Niobate Synthesized with Wet Chemical Deposition

We have measured the cross‐plane thermal conductivity (κ) of (010)‐textured, undoped, and lanthanum‐doped strontium niobate (Sr2−xLaxNb2O7−δ) thin films via time‐domain thermoreflectance. The thin films were deposited on (001)‐oriented SrTiO3 substrates via the highly‐scalable technique of chemical...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Ceramic Society 2015-02, Vol.98 (2), p.624-628
Hauptverfasser: Foley, Brian M., Brown-Shaklee, Harlan J., Campion, Michael J., Medlin, Douglas L., Clem, Paul G., Ihlefeld, Jon F., Hopkins, Patrick E.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We have measured the cross‐plane thermal conductivity (κ) of (010)‐textured, undoped, and lanthanum‐doped strontium niobate (Sr2−xLaxNb2O7−δ) thin films via time‐domain thermoreflectance. The thin films were deposited on (001)‐oriented SrTiO3 substrates via the highly‐scalable technique of chemical solution deposition. We find that both film thickness and lanthanum doping have little effect on κ, suggesting that there is a more dominant phonon scattering mechanism present in the system; namely the weak interlayer‐bonding along the b‐axis in the Sr2Nb2O7 parent structure. Furthermore, we compare our experimental results with two variations of the minimum‐limit model for κ and discuss the nature of transport in material systems with weakly‐bonded layers. The low cross‐plane κ of these scalably‐fabricated films is comparable to that of similarly layered niobate structures grown epitaxially.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.13318