Hybrid Uranium-Oxalate Fullerene Topology Cage Clusters

Hybrid Uranium-Oxalate Fullerene Topology Cage Clusters

Fullerene′s topology: Inorganic–organic hybrid cage clusters containing 36 and 60 uranyl peroxide polyhedra and 6 or 30 oxalate groups (see representation of a {U60} cluster) self‐assemble in aqueous solution under ambient conditions. These clusters, which are derivatives of fullerene topologies, we...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-09, Vol.49 (40), p.7271-7273
Hauptverfasser: Ling, Jie, Wallace, Christine M, Szymanowski, Jennifer E.S, Burns, Peter C
Format: Artikel
Sprache:eng
Schlagworte:
actinides
fullerenes
MATERIALS SCIENCE
nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
peroxides
polyoxometalates
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Zusammenfassung:Fullerene′s topology: Inorganic–organic hybrid cage clusters containing 36 and 60 uranyl peroxide polyhedra and 6 or 30 oxalate groups (see representation of a {U60} cluster) self‐assemble in aqueous solution under ambient conditions. These clusters, which are derivatives of fullerene topologies, were crystallized for structure analysis, and are readily dissolved intact in water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003197