The pressure dependence of oxygen-isotope-exchange rates between solution and apical oxygens on the UO2(OH)42- ion

The pressure dependence of isotope exchange rate was determined for apical oxygen atoms in the UO2(OH)42-(aq) ion. The results can be interpreted to indicate an associative character of the reaction.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2011-04, Vol.50 (19)
Hauptverfasser:	Harley, Steven J., Ohlin, C. Andre, Johnson, Rene L., Panasci, Adele F., Casey, William H.
Format:	Artikel
Sprache:	eng
Schlagworte:	INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY materials and chemistry by design nuclear (including radiation effects) synthesis (novel materials) synthesis (self-assembly)
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Beschreibung
Zusammenfassung:	The pressure dependence of isotope exchange rate was determined for apical oxygen atoms in the UO2(OH)42-(aq) ion. The results can be interpreted to indicate an associative character of the reaction.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201006961