Catalytic Oxy-Functionalization of Methane and Other Hydrocarbons: New Fundamental Advancements and Strategies

Catalytic Oxy-Functionalization of Methane and Other Hydrocarbons: New Fundamental Advancements and Strategies

The controlled conversion of methane to methanol requires C-H bond cleavage and C-O bond formation. A catalytic cycle incorporating 1,2-CH-addition and net oxygen insertion with late transition metals has been proposed for this conversion. This Minireview discusses the current state of the art for e...

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Veröffentlicht in:ChemSusChem 2011-01, Vol.4 (1)
Hauptverfasser: Webb, Joanna R, Bolano, Tamara, Gunnoe, T. Brent
Format: Artikel
Sprache:eng
Schlagworte:
catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)
HOMOGENEOUS CATALYSIS
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
METHANOL
OXIDATION
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Zusammenfassung:The controlled conversion of methane to methanol requires C-H bond cleavage and C-O bond formation. A catalytic cycle incorporating 1,2-CH-addition and net oxygen insertion with late transition metals has been proposed for this conversion. This Minireview discusses the current state of the art for each step of the proposed catalytic cycle.
ISSN:1864-5631
1864-564X
DOI:10.1002/cssc.201190000