The existence of memory effect on hydrogen ordering in ice: The effect makes ice attractive

The existence of ferroelectric ice XI with ordered hydrogen in space becomes of interest in astronomy and physical chemistry because of the strong electrostatic force. However, the influence was believed to be limited because it forms in a narrow temperature range. From neutron diffraction experimen...

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Veröffentlicht in:Geophysical research letters 2011-08, Vol.38 (16), p.n/a
Hauptverfasser: Arakawa, Masashi, Kagi, Hiroyuki, Fernandez-Baca, Jaime A., Chakoumakos, Bryan C., Fukazawa, Hiroshi
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Sprache:eng
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Zusammenfassung:The existence of ferroelectric ice XI with ordered hydrogen in space becomes of interest in astronomy and physical chemistry because of the strong electrostatic force. However, the influence was believed to be limited because it forms in a narrow temperature range. From neutron diffraction experiments, we found that small hydrogen‐ordered domains exist at significantly higher temperature and the domains induce the growth of “bulk” ice XI. The small ordered domain is named “memory” of hydrogen ordered ice because it is the residual structure of ice XI. Since the memory exists up to at least 111 K, most of ices in the solar system are hydrogen ordered and may have ferroelectricity. The small hydrogen‐ordered domains govern the cosmochemical properties of ice and evolution of icy grains in the universe. Key Points Small hydrogen‐ordered domains with ferroelectricity exist in normal ice Ferroelectric ordered ice exist in wider area in space than ever believed Small ordered domains could govern the evolution of icy grains in space
ISSN:0094-8276
1944-8007
DOI:10.1029/2011GL048217