Kinetic Control of Metal-Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering

Kinetic Control of Metal-Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering

MOFs scattering away: The mechanism behind the multistep synthesis of two metal–organic frameworks sharing the same metal and organic precursors was revealed by in situ time‐resolved small‐ and wide‐angle X‐ray scattering. Key factors governing the crystal assembly could be established (see picture:...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2011-10, Vol.50 (41), p.9624-9628
Hauptverfasser: Stavitski, Eli, Goesten, Maarten, Juan-Alcañiz, Jana, Martinez-Joaristi, Alberto, Serra-Crespo, Pablo, Petukhov, Andrei V., Gascon, Jorge, Kapteijn, Freek
Format: Artikel
Sprache:eng
Schlagworte:
CRYSTALLIZATION
crystallization kinetics
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KINETICS
metal-organic frameworks
MIL-101
MIL-53
PRECURSOR
SAXS/WAXS
SCATTERING
SMALL ANGLE SCATTERING
SYNTHESIS
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Zusammenfassung:MOFs scattering away: The mechanism behind the multistep synthesis of two metal–organic frameworks sharing the same metal and organic precursors was revealed by in situ time‐resolved small‐ and wide‐angle X‐ray scattering. Key factors governing the crystal assembly could be established (see picture: C gray, H white, N blue, O red, Al yellow, Cl green), including solvent, temperature, and precursor concentration.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201101757