Catalytic pyrolysis of waste oil into hydrocarbon fuel utilizing cerium oxide catalyst

The depletion of fossil fuels has prompted research into alternative fuels made from regeneration of waste materials. Pyrolysis is a method of converting waste oil into valuable products, such as char, gas, and fuel. This study presents the catalytic pyrolysis of waste oil for producing fuel utilizi...

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Veröffentlicht in:The Korean journal of chemical engineering 2022, 39(6), 267, pp.1487-1495
Hauptverfasser: Khalid, Mohamad Arsyad Abdul, Abdullah, Nurhayati, Ibrahim, Mohamad Nasir Mohamad, Taib, Rahmad Mohd, Rosid, Salmiah Jamal Mat, Shukri, Nurasmat Mohd, Yahaya, NoorFatimah, Abdullah, Wan Nazwanie Binti Wan
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Sprache:eng
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Zusammenfassung:The depletion of fossil fuels has prompted research into alternative fuels made from regeneration of waste materials. Pyrolysis is a method of converting waste oil into valuable products, such as char, gas, and fuel. This study presents the catalytic pyrolysis of waste oil for producing fuel utilizing cerium oxide, CeO 2 /Al 2 O 3 and zinc oxide, ZnO/Al 2 O 3 catalyst. The catalyst and oil were characterized using several characterization techniques to find the physicochemical properties of the catalyst and oil. The optimum condition for catalytic pyrolysis was a reaction temperature at 500 °C, with the heating rate at 10 °C/min, utilizing CeO 2 /Al 2 O 3 catalyst calcined at 700 °C. The catalytic pyrolysis successfully converted the waste oil into fuel and the oil product obtained was 93.01 wt% with a high calorific value (54.2 MJ/kg). The pyrolysis oil is comprised of aliphatic hydrocarbon (C 5 –C 15 hydrocarbon) that is within the hydrocarbon range for gasoline and diesel. The oil product was also detected to have a low content of oxygen (3.07 wt%) and sulfur (0.60 wt%), indicating its potential to serve as a cleaner, fuel reducing the sulfur dioxide, SO X formation. The results reveal that pyrolysis reactors have the ability to convert waste oil into hydrocarbon fuel.
ISSN:0256-1115
1975-7220
DOI:10.1007/s11814-022-1091-6