Piezoelectric and magnetoelectric properties of PVDF/NiFe2O4 based electrospun nanofibers for flexible piezoelectric nanogenerators

In this study, flexible piezoelectric nanogenerators (PNGs) were fabricated using the composite fibers which were prepared by combining polyvinylidene difluoride (PVDF) and nickel ferrite (NiFe2O4) nanoparticles (NPs) at a concentration of 1, 3, 5, 7, and 10 wt%. The piezoelectric properties of PNG indicate that the PVDF/NiFe2O4 fibers containing NiFe2O4 NPs at a concentration of 10 wt% has a higher power efficiency of 5.4% at 20 Hz compared to that of the pure PVDF fibers at 10 Hz, under the same resistive load of 2.5 MΩ. The magnetoelectric properties of PNG show that the PNG with PVDF+7 wt%NiFe2O4 supplied the highest electrical power of 0.40 μW under a resistive load of 750KΩ while it reached a maximum voltage value of 17.50 mV at the same load resistive load for a low-level magnetic field of 50 Hz frequency. [Display omitted] 1.PVDF/NiFe2O4 electrospun fibers were fabricated by the electrospinning.2.Aligned electrospun fibers by rotating collector exhibited a rich β-phase content.3.The piezoelectric-magnetoelectric properties of nanogenerators were investigated.4.The first time, the vibration sense frequency of PVDF/NiFe2O4 was found as 20 Hz.