Degradation Mechanism of Interfacial Adhesion between Screen-Printed Ag/Polyimide in Temperature/Humidity Environment

The effect of temperature/humidity (T/H) treatment at 85 ℃/85% relative humidity (R.H.) on the peel strength between screen-printed Ag/polyimide (PI) substrate was evaluated using a 180° peel test. Initial peel strength was 22.22 ± 1.00 gf/mm, and then decreased to 0.47 ± 0.22 gf/mm after 500 h at 8...

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Veröffentlicht in:Electronic materials letters 2021, 17(2), , pp.157-163
Hauptverfasser: Bae, Byung-Hyun, Lee, Hyeonchul, Kim, Gahui, Son, Kirak, Park, Young-Bae
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Sprache:eng
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Zusammenfassung:The effect of temperature/humidity (T/H) treatment at 85 ℃/85% relative humidity (R.H.) on the peel strength between screen-printed Ag/polyimide (PI) substrate was evaluated using a 180° peel test. Initial peel strength was 22.22 ± 1.00 gf/mm, and then decreased to 0.47 ± 0.22 gf/mm after 500 h at 85 ℃/85% R.H. treatment condition. And, the peeled locus was changed from Ag/PI interface to mixed mode of Ag/PI interface and shallow cohesive inside PI near Ag/PI interface. The decrease in peel strength during T/H treatment is related to formation of weak boundary layer inside PI near Ag/PI interface by hydrolytic degradation of PI due to long-term moisture penetration into the Ag/PI interface. Graphic abstract
ISSN:1738-8090
2093-6788
DOI:10.1007/s13391-021-00272-1