Hierarchical K/LTL zeolites: Synthesis by alkali treatment, characterization and catalytic performance in Knoevenagel condensation reaction

[Display omitted] The hierarchical K/LTL zeolites prepared by post-synthesis modification with aqueous 1.5M KOH solution by varying alkali volume to K/LTL zeolite (10⿿70ml/g) ratios, were examined in Knoevenagel condensation. The physico-chemical properties of the catalysts were thoroughly evaluated by PXRD, FTIR, ICP, CO2-TPD, XPS, N2 adsorption/desorption and 29Si and 27Al MAS-NMR. Among all the samples, hierarchical K/LTL prepared by treating K/LTL with 50ml aqueous 1.5M KOH solution per gram of K/LTL displayed about 1.5 fold higher catalytic activity as compared to parent K/LTL, presumably because of combined effect of enhanced basicity and molecular diffusion through pore channels.