Comparison of synthesized H-Al-MCM-41 with different Si/Al ratios for benzene reduction in gasoline with propylene
Benzene reduction in gasoline was investigated with propylene over synthesized mesoporous H-Al-MCM-41 with Si/Al=15, 29 and 42 as catalysts in order to produce more environmental friendly gasoline. The resulting catalysts were characterized by XRF, XRD, FTIR, TGA, BET and TPD-NH3 techniques. The res...
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Veröffentlicht in: | Journal of industrial and engineering chemistry (Seoul, Korea) 2015, 24(0), , pp.113-120 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Benzene reduction in gasoline was investigated with propylene over synthesized mesoporous H-Al-MCM-41 with Si/Al=15, 29 and 42 as catalysts in order to produce more environmental friendly gasoline. The resulting catalysts were characterized by XRF, XRD, FTIR, TGA, BET and TPD-NH3 techniques. The results of alkylation of C6-cut obtained from gasoline indicated that the synthesized mesoporous H-AL-MCM-41 with Si/Al=15 is the most active catalyst among the synthesized catalysts due to high crystallinity, favorable textural properties and large bronsted acidity. The higher conversion of benzene (47.88%) was observed over H-Al-MCM-41 with Si/Al=15 at B/P=1 and T=200°C. |
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ISSN: | 1226-086X 1876-794X |
DOI: | 10.1016/j.jiec.2014.09.017 |