Multi-Electron Donor Organic Molecules Containing Hydroquinone Methyl-Ether as Redox Active Units

Three hydroquinone dimethyl ether derivatives have been synthesized and characterized by X-ray diffraction. The electron donating properties were evaluated by using UV-vis spectroscopy, cyclic voltammetry and by ESR spectroscopy. The microcrystalline cation-radical salts of the three donor molecules...

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Veröffentlicht in:Bulletin of the Korean Chemical Society 2012, 33(4), , pp.1190-1198
Hauptverfasser: Khandelwal, Manish, Hwang, In-Chul, Nair, Prakash Chandran R., Lee, Jung-Woo
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Sprache:eng
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Zusammenfassung:Three hydroquinone dimethyl ether derivatives have been synthesized and characterized by X-ray diffraction. The electron donating properties were evaluated by using UV-vis spectroscopy, cyclic voltammetry and by ESR spectroscopy. The microcrystalline cation-radical salts of the three donor molecules were also isolated by using antimony pentachloride, a single electron Lewis acid oxidant. KCI Citation Count: 1
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2012.33.4.1190