Asymmetric Synthesis of (+)-trans-Aerangis Lactone

Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis....

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Veröffentlicht in:Bulletin of the Korean Chemical Society 2013, 34(1), , pp.75-78
Hauptverfasser: Kim, Aejin, Sharma, Satyasheel, Kwak, Jong Hwan, Kim, In Su
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Sprache:eng
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Zusammenfassung:Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis. KCI Citation Count: 6
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2013.34.1.75