Efficient Synthesis of Spirobarbiturates and Spirothiobarbiturates Bearing Cyclopropane Rings by Rhodium(II)-Catalyzed Reactions of Cyclic Diazo Compounds

Rhodium(II)-catalyzed reactions of cyclic diazo compounds derived from barbituric acid and thiobarbituric acid with a variety of styrene moieties were examined. These reactions provide rapid synthetic routes to the preparations of spirobarbiturates and spirothiobarbiturates bearing cyclopropane ring...

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Veröffentlicht in:Bulletin of the Korean Chemical Society 2013, 34(6), , pp.1735-1740
Hauptverfasser: Wang, Xue, Lee, Yong Rok
Format: Artikel
Sprache:eng
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Zusammenfassung:Rhodium(II)-catalyzed reactions of cyclic diazo compounds derived from barbituric acid and thiobarbituric acid with a variety of styrene moieties were examined. These reactions provide rapid synthetic routes to the preparations of spirobarbiturates and spirothiobarbiturates bearing cyclopropane rings. KCI Citation Count: 7
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2013.34.6.1735