Two New Bithiophenes Derivatives Multielectrochromic Copolymer Based on Triphenylamine Unit and Their Application for Electrochromic Devices

Two monomers including 4,4′,4″‐tris(3‐methoxythiophene‐2‐yl)triphenylamine (M1) and 4,4′,4″‐tris(3,4‐dimethoxythiophene‐2‐yl)triphenylamine (M2) with triphenylamine as their core were synthesized and the corresponding polymers were obtained by electrochemical polymerization. Their electrochemical properties were investigated using scanning electron microscopy, UV–Vis, and cyclic voltammetry. It was found that the two polymers had reversible redox behavior with the different color change under the applied potentials. Both the polymers displayed high switching efficiency and optical contrast. Moreover, the corresponding electrochromic devices (ECDs) employing the synthesized polymers and poly(3,4‐ethylenedioxythiophene) were constructed. The spectroelectrochemical experiments illustrated that the ECDs exhibited fast response time, reasonable optical contrast, favorable optical memories, and redox stability. Two new triphenylamine‐based electrochromic polymer films including different methoxythiophene substituents have been synthesized by electrochemical polymerization. The polymer films have multiple colors at different applied potential from neutral state to oxidized state, and exhibit short response time (