Efficient continuous epoxidation of biodiesel in a microstructured reactor

Efficient continuous epoxidation of biodiesel in a microstructured reactor

Efficient continuous epoxidation of biodiesel with peracetic acid generated in situ from hydrogen peroxide and acetic acid was studied in detail in a microstructured reactor. The effects of micromixer type, reaction temperature, catalyst usage, flow rate and residence time were considered. Results s...

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Veröffentlicht in:The Korean journal of chemical engineering 2016, 33(9), 198, pp.2622-2627
Hauptverfasser: Yao, Xingjun, Zhang, Yan, Du, Lingyun, Liu, Huiqiang, Jiang, Song
Format: Artikel
Sprache:eng
Schlagworte:
Acetic acid
Biodiesel fuels
Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Environmental Engineering
Epoxidation
Hydrogen peroxide
Industrial Chemistry/Chemical Engineering
Iodine
Materials Science
Peracetic acid
화학공학
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Zusammenfassung:Efficient continuous epoxidation of biodiesel with peracetic acid generated in situ from hydrogen peroxide and acetic acid was studied in detail in a microstructured reactor. The effects of micromixer type, reaction temperature, catalyst usage, flow rate and residence time were considered. Results show the T-type glass micro-structured reactor (TTGMR) outperforms the interdigital multilamination micromixer. Under the optimized conditions, the final product from TTGMR has an epoxy value of 6.5 and an iodine value of 2.2.
ISSN:0256-1115
1975-7220
DOI:10.1007/s11814-016-0115-5