An investigation of adsorption parameters on ZVI-AC nanocomposite in the displacement of Se(IV) ions through CCD analysis
[Display omitted] •The ZVI-AC nanocomposite in 10 μm has been constructed as an excellent transporter of Se(IV) ions.•The morphology and interfacial characteristics of components of nanocomposite has been investigated.•A four-factor central composite design was examined for independent adsorption pr...
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Veröffentlicht in: | Journal of industrial and engineering chemistry (Seoul, Korea) 2019, 75(0), , pp.211-223 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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•The ZVI-AC nanocomposite in 10 μm has been constructed as an excellent transporter of Se(IV) ions.•The morphology and interfacial characteristics of components of nanocomposite has been investigated.•A four-factor central composite design was examined for independent adsorption process variables.•Langmuir adsorption capacity was measured as 34.77 mg/g.•The average diffusivity of Se(IV) is 1.40 × 10−5 m2/s.
In this research, a 10 μm nanocomposite was built on the solid carbon used from brew squander with 72.24% carbon (atomic %). On the surface of activated carbon, iron nanoparticles were stacked up to settle the composite. The prepared composite was used to remove Se(IV) from wastewater. A four-factorial central composite design was anticipated, broke down through ANOVA for testing adsorption with optimum operational conditions. Adsorption isotherm study for the present system produces 34.77 mg/g binding capacity of 2.75 g/L nanocomposite to Se(IV) ions. The present system was exothermic, unconstrained, obeys both intra-particle and shrinking core diffusion models. |
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ISSN: | 1226-086X 1876-794X |
DOI: | 10.1016/j.jiec.2019.03.026 |