Conductivity relaxation in NiTiO3 at high temperatures

NiTiO3 ceramics were prepared via the traditional solid-state reaction route. The dielectric properties of NiTiO3 ceramics have been systematically investigated in the temperature range from room temperature to 1073 K NiTiO3 ceramics exhibit intrinsic dielectric response in the temperature range bel...

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Veröffentlicht in:Current applied physics 2013, 13(8), , pp.1728-1731
Hauptverfasser: Li, Teng, Wang, Chun Chang, Lei, Chang Mei, Sun, Xiao Hong, Wang, Guo Jing, Liu, Liu Na
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Sprache:eng
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Zusammenfassung:NiTiO3 ceramics were prepared via the traditional solid-state reaction route. The dielectric properties of NiTiO3 ceramics have been systematically investigated in the temperature range from room temperature to 1073 K NiTiO3 ceramics exhibit intrinsic dielectric response in the temperature range below 400 K. Two relaxations were observed in the temperature range higher than 400 K. The relaxation activation energy is 0.95 eV and 1.17 eV for the low- and high-temperature relaxations, respectively. Our results strongly indicate that the two relaxations are related to conductivity relaxation associated with the singly and doubly ionized oxygen vacancies. •NiTiO3 shows intrinsic dielectric response in the temperature range below 400 K.•The two relaxations are related to conductivity relaxation.•Oxygen vacancies from singly to doubly charged states are around 700 K in NiTiO3.
ISSN:1567-1739
1878-1675
DOI:10.1016/j.cap.2013.07.002